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Corundum crystals and gems - oxidesCorundum crystals and gems - oxides

Mineralogy of Oxides and Hydroxides


Oxides and hydroxides are mineral classes that include well-known gems as well as significant ores. Learn how to identify these minerals.

14 Minute Read

By Olena Rybnikova, PhD, updated on
Corundum crystals and gems - oxides
Corundum crystals and faceted gemstones (sapphire variety). Photo © International Gem Society/Olena Rybnikova, PhD.

Introduction to Oxide and Hydroxide Mineral Classes

The oxide and hydroxide classes can serve as an instructive connection between primarily metallic opaque and dark-colored native element and sulfide minerals and vitreous, transparent, and light-colored silicate minerals. While studying oxides and hydroxides, we will encounter both opaque dark-colored ore minerals and sparkling transparent gemstones.

There are 395 mineral species in the oxide and hydroxide classes. (Klein & Dutrow, 2007) We will cover the most essential and common membeers. To understand why oxides and hydroxides are studied together as well as their differences, we must consider their chemistry. Take a look at the formulas in the following table. Oxides and hydroxides have identical metallic cations. The only difference is their anions: O2- for oxides and (OH) for hydroxides.

Metal cationOxideHydroxide
Iron Fe3+Hematite Fe2O3, magnetite Fe3O4Goethite α–FeO(OH), Lepidocrocite γ–FeO(OH)
Aluminum Al3+Corundum Al2O3Gibbsite γ–Al(OH)3, Böhmite Al(OH)3, Diaspore α–Al(OH)3
Manganese Mn4+, Mn3+Pyrolusite Mn

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